Organic chemistry

A.Y. 2020/2021
6
Max ECTS
56
Overall hours
SSD
CHIM/06
Language
Italian
Learning objectives
Organic substances such as fundamental building blocks of living material. We will describe the structure, the physical-chemical properties and reactivity of the major classes of organic compounds, with particular emphasis on those most important in food matrices.
Expected learning outcomes
1. Knowledge of basic classification and nomenclature of organic compounds, as fundamental building blocks of living material. 2. Understanding of the relationships that exist between the chemical formula, three-dimensional structure and physical-chemical properties (solubility, volatility, color, etc..) of organic molecules. 3. Knowledge of the main reactions of organic compounds: acid-base reactions, oxidation-reduction, hydrolysis, etc. radical reactions.
Course syllabus and organization

Single session

Responsible
Lesson period
Second semester
The Microsoft Teams platform is used for the lessons and the students can follow the lessons synchronously on the basis of the second semester timetable. Asynchronous recordings (Power Point with audio) will also be available. The program and reference material will not be affected.
The remot exams will be carried out using the Microsoft Teams platform in oral form, in the manner illustrated on the University portal. The candidate will have to carry out exercises and answer theory questions. The candidate's correctness of expression and good use of chemical language will be evaluated. Furthermore, the ability to connect between the various topics covered in the course will be evaluated. The vote will be expressed out of 30.
Course syllabus
The organic compounds: structure, isomerism, compact formula, functional group. Intermolecular bonds in the organic compounds and their relationship with chemical-physical proprieties: volatility, solubility, etc. Alkanes and cycloalkanes: conformational analysis; chemical-physical proprieties; radical reactions; radical's stability. Alkenes: structure, proprieties, geometric isomerism. Dienes and polyenes (short account). Addition reactions of alkenes: electrophilic and nucleophilic reagents. Radical reactions of alkenes. Alkanes and alkenes in nature: terpenes (short account). Aromatic compounds: some derivative of benzene, polycycles and heterocyclic aromatic compounds. nomenclature and structure of aromatic compounds. Alkyl halides: structure, reactivity, proprieties and ecological problems. Alcohols: structure, proprieties, acidity and redox reactions. Phenols: structure, proprieties, acidity and redox reactions. Antioxidants. Other oxigenated derivatives: quinones ethers, epoxides. Organosulfur compounds compounds: thiols and disulfur derivatives. Chirality and optical activity, absolute and relative configuration. Enantiomers, diasteroisomers and racemic mixtures. Relationship between biological proprieties and optical active compounds. CFC and ozone's hole. Aldehydes and ketones: structure, proprieties, redox and nucleophic addition reactions. Semiacetals, acetals and hydrated derivative of aldehydes and ketones. Some typical carbonyl addition reactions of nitrogen nucleophilic reagent. Carbohydrates: mono-, di- and polysaccharides. Monosaccharides: structure and Fisher projections, stereochemistry. Cyclic structure and mutarotation. Disaccharides and polysaccharides: proprieties and importance in biological system. Carboxylic acids: proprieties and reactions. Funcional derivatives of carboxilyc acids: acid halides, esters, amides, anhydrides, carbammates, uree. Reactions of nucleophilic displacements: esterifications and hydrolysis of esters and amides. Lipids: fatty acids, triglycerids, phospholipids. Soap and tensioactives. Amines: structure, proprieties, basicity. Natural nitrogen containing compounds (short account). Aminoacids and peptide bond, pI. Peptides and proteins. Exercises in preparation to the exam.
Prerequisites for admission
Inorganic and General Chemistry
Teaching methods
Lectures ( 5FCU) and practical laboratory activities (1CFU).
Teaching Resources
Course slides.
Recommended texts: P. Y. Bruice, Elements of Organic Chemistry (Edises). Includes ebook version.
W. Brown, T. Poon, Introduction to organic chemistry (Edises). Includes molecular models.
F. S. Lee, Guide to solving problems from: W. Brown, T. Poon, Introduction to organic chemistry (Edises).
Assessment methods and Criteria
The exam consists of a one and a half hour written test (20 questions with a closed answer) and an oral exam (30 minutes) subject to passing the preceding test. 12 correct answers out of 20 mean the candidate has passed. The correct answers are worth 1 point, wrong answers or not given are worth 0 points. The test results will be communicated via the Ariel platform. During the oral examination the correctness of the candidate's language and of the chemical terms will be evaluated. Furthermore, the ability to link the various topics covered in the course will be evaluated. The vote will be out of 30. The test includes all the topics of the course plus those covered in the laboratory. Students with DSA certification are required to promptly notify the Teacher to agree with the methods of examination. Students enrolled in an exam session and no longer wishing to support it are required to unsubscribe.
CHIM/06 - ORGANIC CHEMISTRY - University credits: 6
Laboratories: 16 hours
Lessons: 40 hours
Professor: Mazzini Stefania
Professor(s)
Reception:
Tuesday from 15.30 to 17.30
DISMA