Structural Chemistry
A.Y. 2019/2020
Learning objectives
The course provides an introduction to X-ray diffraction structural techniques, paying particular attention to experimental aspects and interpretation of data. The aim of the course is therefore to make the student understand what structural information can be obtained and how from this type of investigation.
Expected learning outcomes
Students will gain ability to interpret and use structural information of crystalline substances.
Lesson period: Second semester
Assessment methods: Esame
Assessment result: voto verbalizzato in trentesimi
Single course
This course cannot be attended as a single course. Please check our list of single courses to find the ones available for enrolment.
Course syllabus and organization
Single session
Course syllabus
Course content: Crystal Systems and Symmetry. The International Tables for X-ray crystallography. X-ray production. The crystal lattice. X-ray diffraction. Bragg's Law. Powder diffraction as useful analytical tool for phase identification. The reciprocal lattice. Structure factors and Fourier Syntheses. Experimental methods for single-crystal structure determination. Structure solution and refinement. Interpretation of results. Crystallographic Databases.
Fundamental aspects of growth processes: a) Homogeneous and heterogeneous nucleation; b) supersaturation and mass transport; kinetics and mechanisms of crystal growth; c) crystal growth techniques from solution. Morphology of the crystals: crystal classes, crystal forms and Miller indices. Theories for crystal habit prediction.
Fundamental aspects of growth processes: a) Homogeneous and heterogeneous nucleation; b) supersaturation and mass transport; kinetics and mechanisms of crystal growth; c) crystal growth techniques from solution. Morphology of the crystals: crystal classes, crystal forms and Miller indices. Theories for crystal habit prediction.
Prerequisites for admission
None
Teaching methods
Traditional. The slides used during the lessons will be provided to the students.
Teaching Resources
G.H. Stout & L.H. Jensen "X-ray Structure Determination: a practical guide" Macmillan Publishing Co. Inc. New York.
Werner Massa "Crystal Structure Determination" Springer-Verlag, Berlin.
R. Davey and J. Garside "From molecules to crystallizer: an introduction to crystallization" ed. Oxford Science Publication
Werner Massa "Crystal Structure Determination" Springer-Verlag, Berlin.
R. Davey and J. Garside "From molecules to crystallizer: an introduction to crystallization" ed. Oxford Science Publication
Assessment methods and Criteria
The exam consists of an oral discussion covering all the subjects discussed in the course to verify both the gained knowledge and the ability of critical analysis of the covered topics.
CHIM/03 - GENERAL AND INORGANIC CHEMISTRY - University credits: 6
Practicals: 16 hours
Lessons: 40 hours
Lessons: 40 hours
Professors:
Demartin Francesco, Rizzato Silvia
Shifts:
-
Professors:
Demartin Francesco, Rizzato SilviaProfessor(s)
Reception:
Wednesday and Friday 16:00-17:00. Please send an e-mail.
Dipartimento di Chimica, Corpo A, stanza 1402