Analytical chemistry with elements of chemometrics

A.Y. 2021/2022
7
Max ECTS
64
Overall hours
SSD
CHIM/01
Language
Italian
Learning objectives
The educational objective of the course is to provide students the basic principles in analytical chemistry, especially concerning ionic equilibria in aqueous solution. Aim of the course is the introduction of the statistic/chemometric techniques necessary for processing the experimental data acquired in a laboratory of analytical chemistry. Moreover, the course will also provide students the practical information for operating in a chemical laboratory.
Expected learning outcomes
At the end of the course the students will be able to calculate concentrations in solution from equilibrium constants by a systematic approach. The student will be also able to use the basic statistical/chemometric techniques required for extracting/ elaborating / optimising the information collected by experimental measurements. Moreover, the student will have acquired the knowledge to work in a chemical laboratory.
Course syllabus and organization

Single session

Responsible
Lesson period
First semester
Depending on the emergency level:
a) Lessons held regularly in the classroom (reservations will be available through an app developed by the university). Information on the course website. Lessons will be also available on Microsoft Teams.
b) Lessons held on Microsoft Teams (videorecording will also be available).
In both cases, laboratory training on reservation through the faculty system.
More information on the Ariel course website at the beginning of the semester.
Course syllabus
Introduction to analytical chemistry. The overall analytical procedure. Chemical equilibrium. Acids and bases. Calculations of equilibria in aqueous solution by solving simultaneous equations: pH of solutions containing strong or weak acid and bases, acidic salts, polyprotic acids, buffers. Precipitation and solubility. Complexes and chelates. Mixed equilibria. Theory and application of acid-base, precipitation and complexation titrations. Introduction to electrochemistry. Electrodes and electrode potentials. Nernst's equation. Electrodes classification Potentiometry. pH measurement. Operative definition of pH. Chemicals, glassware and analytical instrumentation. Safety in the chemical laboratory. Foundations of Chemometrics. Errors in chemical analysis. Processing of analytical data (significance tests, calibration). Procedures for improving experimental data quality. Laboratory experiments (acid-base and complexation titrations). Use of Excel worksheets in the chemical lab.
Prerequisites for admission
Basic knowledge of chemistry and mathematics.
Teaching methods
Classroom lectures and laboratory training.
Teaching Resources
Slides available on Ariel platform. Recommended book: Chimica Analitica e Analisi Quantitativa, Hage & Carr, Piccin, 2012.
Assessment methods and Criteria
Written exam consisting of multiple choice questions and exercises.
CHIM/01 - ANALYTICAL CHEMISTRY - University credits: 7
Laboratories: 16 hours
Lessons: 48 hours
Professor: Brunetti Barbara